金属有机框架(MOFs)是一种被广泛研究的多孔纳米材料,由金属离子/簇与有机配体通过配位相互作用构成,代表了目前新功能材料最快速发展的平台之一。基于其成熟的合成方法、较高的比表面积、可调的孔径和模块化的设计,可以很容易地合成具有多种功能的MOFs材料。重点介绍了MOFs的合成方法及其最新的应用领域。
Metal organic frameworks (MOFs) are widely studied porous nanomaterials,which are an organic-inorganic hybrid solid composed of metal ions/clusters and organic ligands through coordination interactions,representing one of the fastest development platforms of new functional materials.Based on its mature synthesis method,high surface area,adjustable aperture,modular features and design adaptability,the MOFs can be easily controlled to have multiple functions.The synthesis of MOFs and latest applications in recent years were focused on.
[1] Seetharaj R, Vandana P V, Arya P, et al.Dependence of solvents, pH, molar ratio and temperature in tuning metal organic framework architecture[J].Arabian Journal of Chemistry, 2016, 12(3):295-315.
[2] Tu T N, Nguyen M V, Nguyen H L, et al.Designing bipyridine-functionalized zirconium metal-organic frameworks as a platform for clean energy and other emerging applications[J].Coordination Chemistry Reviews, 2018, 364:33-50.
[3] Evans J D, Garai B, Reinsch H, et al.Metal-organic frameworks in Germany:from synthesis to function[J].Coordination Chemistry Reviews, 2018, 380:378-418.
[4] Vaitsis C, Sourkouni G, Argirusis C, et al.Metal organic frameworks (MOFs) and ultrasound:a review[J].Ultrasonics Sonochemistry, 2018, 52:106-119.
[5] Qiu Q, Chen H, Wang Y, et al.Recent advances in the rational synthesis and sensing applications of metal-organic framework biocomposites[J].Coordination Chemistry Reviews, 2019, 387:60-78.
[6] Duan J, Pan Y, Liu G, et al.Metal-organic framework adsorbents and membranes for separation applications[J].Current Opinion in Chemical Engineering, 2018, 20:122-131.
[7] He H, Hashemi L, Hu M, et al.The role of the counter-ion in metal-organic frameworks' chemistry and applications[J].Coordination Chemistry Reviews, 2018, 376:319-347.
[8] Jiao J, Gong W, Wu X, et al.Multivariate crystalline porous materials:synthesis, property and potential application[J].Coordination Chemistry Reviews, 2019, 385:174-190.
[9] Kang Y S, Lu Y, Chen K, et al.Metal-organic frameworks with catalytic centers:from synthesis to catalytic application[J].Coordination Chemistry Reviews, 2018:S0010854517304654.
[10] Katoch A, Goyal N, Gautam S.Applications and advances in coordination cages:metal-organic frameworks[J].Vacuum, 2019, 167:287-300.
[11] Cui J, Ren S, Sun B, et al.Optimization protocols and improved strategies for metal-organic frameworks for immobilizing enzymes:current development and future challenges[J].Coordination Chemistry Reviews, 2018, 370:22-41.
[12] Wu D, Xu F, Sun B, et al.Design and preparation of porous polymers[J].Chemical Reviews, 2012, 112(7):3959.
[13] Mueller U, Schubert M, Teich F, et al.Metal-organic frameworks-prospective industrial applications[J].ChemInForm, 2006, 16(7):626-636.
[14] Muller U, Putter H, Hesse M, et al.Method for electrochemical production of a crystalline porous metal organic skeleton material:US, 7968739B2[P].2011-06-28.
[15] 刘文贤.金属有机框架纳米材料的结构调控及其催化性能研究[D].北京:北京化工大学, 2017.
[16] Zou D, Liu D.Understanding the modifications and applications of highly stable porous frameworks via UiO-66[J].Materials Today Chemistry, 2019, 12:139-165.
[17] Obrien A G, Horvath Z, Levesque F, et al.Continuous synthesis and purification by direct coupling of a flow reactor with simulated moving-bed chromatography[J].Angewandte Chemie International Edition, 2012, 51(28):7028-7030.
[18] Batten M P, Rubiomartinez M, Hadley T D, et al.Continuous flow production of metal-organic frameworks[J].Current Opinion in Chemical Engineering, 2015, 8:55-59.
[19] 韦复华, 梁钊, 姚亮, 等.金属有机框架材料的制备及应用研究进展[J].现代化工, 2017, 37(5):33-37.
[20] Ren J, Dyosiba X, Musyoka N M, et al.Review on the current practices and efforts towards pilot-scale production of metal-organic frameworks (MOFs)[J].Coordination Chemistry Reviews, 2017, 352:187-219.
[21] Khan N A, Hasan Z, Jhung S H.Beyond pristine metal-organic frameworks:preparation and application of nanostructured, nanosized, and analogous MOFs[J].Coordination Chemistry Reviews, 2018, 376:20-45.
[22] Qiu L G, Li Z Q, Wu Y, et al.Facile synthesis of nanocrystals of a microporous metal-organic framework by an ultrasonic method and selective sensing of organoamines[J].Chemical Communications, 2008(31):3642-3644.
[23] Son W J, Kim J, Kim J, et al.Sonochemical synthesis of MOF-5[J].Chemical Communications, 2008, 47(47):6336-6338.
[24] Pichon A, Lazuengaray A, James S L, et al.Solvent-free synthesis of a microporous metal-organic framework[J].Crystengcomm, 2006, 8(3):211-214.
[25] Klimakow M, Klobes P, Thunemann A F, et al.Mechanochemical synthesis of metal-organic frameworks:a fast and facile approach toward quantitative yields and high specific surface areas[J].Chemistry of Materials, 2010, 22(18):5216-5221.
[26] FriAcˇ5iAc＇5 T, Reid D G, Halasz I, et al.Ion- and liquid-assisted grinding:improved mechanochemical synthesis of metal-organic frameworks reveals salt inclusion and anion templating[J].Angewandte Chemie International Edition, 2009, 49(4):712-715.
[27] Leng K, Sun Y, Li X, et al.Rapid synthesis of metal-organic frameworks MIL-101(Cr) without the addition of solvent and hydrofluoric acid[J].Crystal Growth & Design, 2016:acs.cgd.5b01696.
[28] Crawford D E, Casaban J, Haydon R, et al.Synthesis by extrusion:continuous, large-scale preparation of MOFs using little or no solvent[J].Chemical Science, 2015, 6(3):1645-1649.
[29] Calleja G, Sanz R, Orcajo G, et al.Copper-based MOF-74 material as effective acid catalyst in friedel-crafts acylation of anisole[J].Catalysis Today, 2014, 227:130-137.
[30] 徐光利, 刚芳莉, 董涛生, 等.金属有机框架物催化有机反应综述[J].有机化学, 2016, 36(7):1513-1527.
[31] Xu C, Fang R, Luque R, et al.Functional metal-organic frameworks for catalytic applications[J].Coordination Chemistry Reviews, 2019, 388:268-292.
[32] Liao P Q, Shen J Q, Zhang J P.Metal-organic frameworks for electrocatalysis[J].Coordination Chemistry Reviews, 2017, 373:22-48.
[33] Liu Y, Liu Z, Huang D, et al.Metal or metal-containing [emailprotected] nanocomposites as a promising type of photocatalyst[J].Coordination Chemistry Reviews, 2019, 388:63-78.
[34] Gangu K K, Maddila S, Mukkamala S B, et al.Characteristics of MOF, MWCNT and graphene containing materials for hydrogen storage:a review[J].Journal of Energy Chemistry, 2018, 30(3):140-152.
[35] Cui W G, Zhang G Y, Hu T L, et al.Metal-organic framework-based heterogeneous catalysts for the conversion of C1 chemistry:CO, CO2 and CH 4[J].Coordination Chemistry Reviews, 2019, 387:79-120.
[36] Zhang Q, Cui Y, Qian G.Goal-directed design of metal-organic frameworks for liquid-phase adsorption and separation[J].Coordination Chemistry Reviews, 2019, 378:310-332.
[37] Li W.Metal-organic framework membranes:production, modification, and applications[J].Progress in Materials Science, 2018, 100:21-63.
[38] Jiang D, Chen M, Wang H, et al.The application of different typological and structural MOFs-based materials for the dyes adsorption[J].Coordination Chemistry Reviews, 2019, 380:471-483.
[39] Zhong M, Kong L, Li N, et al.Synthesis of MOF-derived nanostructures and their applications as anodes in lithium and sodium ion batteries[J].Coordination Chemistry Reviews, 2019, 388:172-201.
[40] Yijun Z, Xiaomin X, Yu L, et al.Recent progress in metal-organic frameworks for lithium-sulfur batteries[J].Polyhedron, 2018, 155:464-484.
[41] An H, Li M, Ga J, et al.Incorporation of biomolecules in metal-organic frameworks for advanced applications[J].Coordination Chemistry Reviews, 2019, 384:90-106.
[42] Peng J, Wu R.Metal-organic frameworks in proteomics/peptidomics-a review[J].Analytica Chimica Acta, 2018, 1027:9.
[43] Liu Q, Sun N, Deng C H.Recent advances in metal-organic frameworks for separation and enrichment in proteomics analysis[J].TrAC Trends in Analytical Chemistry, 2019, 110:66-80.
[44] Karimi Alavijeh R, Beheshti S, Akhbari K, et al.Investigation of reasons for metal-organic framework's antibacterial activities[J].Polyhedron, 2018, 156:257-278.
[45] Mendiratta S, Usman M, Lu K L.Expanding the dimensions of metal-organic framework research towards dielectrics[J].Coordination Chemistry Reviews, 2018, 360:77-91.
[46] Jiao L, Seow J Y R, Skinner W S, et al.Metal-organic frameworks:structures and functional applications[J].Materials Today, 2018, 27:43-68.
[47] Zheng W, Tsang C, Lee L Y, et al.Two-dimensional metal-organic framework and covalent-organic framework:synthesis and their energy-related applications[J].Materials Today Chemistry, 2019, 12:34-60.
基金资助
上海市科委地方院校能力建设项目(19050502000)
PDF
